Water Balance and Management of a Proton Exchange Membrane Fuel Cell with Different Material Properties and Geometries

Document Type : Original Article

Authors

Faculty of Mechanical and Energy Engineering, Shahid Beheshti University, Tehran, Iran.

Abstract
While studying fuel cells, managing the amount of water and removing its excess, is crutial.  Nano materials used in the membrane, catalyst and gas diffusion layers, as well as the thickness of those layers, could have different effects on water management and cell performance. In the current study, these issues were investigated theoretically with a Proton Exchange Membrane Fuel Cell (PEMFC) with 4-Serpentine flow channels. The geometries of the channels were rectangular and triangular, and the active area of the cell was 24.8cm2. Pure Hydrogen and Oxygen were used on both sides. A complete three-dimensional and two-phase model was used for the numerical solution. To validate the solution, an experimental setup was designed to compare the simulation results with the experimental data, and the outcome was satisfactory. The aftermath shows an increased cell performance either by enhancing the thickness of the gas diffusion layers or reducing the thickness of the membrane in both rectangular and triangular channel geometry. Furthermore, under identical conditions, cell performance with rectangular channel is better than the one with the triangular channel.

Highlights

  • Investigation new geometries of a fuel cell.
  • The effect of geometry on current density and performance.
  • The effect of Nano material properties on current density and performance.
  • Seeing the interacting and complex electrochemical phenomena.

Keywords

Subjects

  1. Larminie, J., Dicks, A., & McDonald, M. S. (2003). Fuel cell systems explained(Vol. 2, pp. 207-225). Chichester, UK: J. Wiley.
  2. Thomas, S., Vang, J. R., Araya, S. S., & Kær, S. K. (2017). Experimental study to distinguish the effects of methanol slip and water vapour on a high temperature PEM fuel cell at different operating conditions. Applied Energy192, 422-436.
  3. Li, J., Li, X., Yu, S., Hao, J., Lu, W., Shao, Z., & Yi, B. (2014). Porous polybenzimidazole membranes doped with phosphoric acid: Preparation and application in high-temperature proton-exchange-membrane fuel cells. Energy conversion and management85, 323-327.
  4. Liso, V., Araya, S. S., Olesen, A. C., Nielsen, M. P., & Kær, S. K. (2016). Modeling and experimental validation of water mass balance in a PEM fuel cell stack. International Journal of Hydrogen Energy41(4), 3079-3092.
  5. Heidary, H., Kermani, M. J., Advani, S. G., & Prasad, A. K. (2016). Experimental investigation of in-line and staggered blockages in parallel flowfield channels of PEM fuel cells. International journal of hydrogen energy41(16), 6885-6893.
  6. Zakaria, I., Azmi, W. H., Mamat, A. M. I., Mamat, R., Saidur, R., Talib, S. A., & Mohamed, W. A. N. W. (2016). Thermal analysis of Al2O3–water ethylene glycol mixture nanofluid for single PEM fuel cell cooling plate: an experimental study. International Journal of Hydrogen Energy41(9), 5096-5112.
  7. Bvumbe, T. J., Bujlo, P., Tolj, I., Mouton, K., Swart, G., Pasupathi, S., & Pollet, B. G. (2016). Review on management, mechanisms and modelling of thermal processes in PEMFC. Hydrogen and Fuel Cells1(1), 1-20.
  8. Wu, H. W. (2016). A review of recent development: Transport and performance modeling of PEM fuel cells. Applied energy165, 81-106.
  9. Daud, W. R. W., Rosli, R. E., Majlan, E. H., Hamid, S. A. A., Mohamed, R., & Husaini, T. (2017). PEM fuel cell system control: A review. Renewable Energy113, 620-638.
  10. Rowshan,Z. S., Eikani, M., Khoshnoodi, M., & Eshagh N. T. (2008). A parametric study of the PEM fuel cell cathode. IUST Int. J. of Engineering Science, 19(2-5), 73-81.
  11. Sasmito, A. P., Kurnia, J. C., & Mujumdar, A. S. (2012). Numerical evaluation of various gas and coolant channel designs for high performance liquid-cooled proton exchange membrane fuel cell stacks. Energy44(1), 278-291.
  12. Xing, L., Liu, X., Alaje, T., Kumar, R., Mamlouk, M., & Scott, K. (2014). A two-phase flow and non-isothermal agglomerate model for a proton exchange membrane (PEM) fuel cell. Energy73, 618-634.
  13. Rostami, L., Nejad, P. M. G., & Vatani, A. (2016). A numerical investigation of serpentine flow channel with different bend sizes in polymer electrolyte membrane fuel cells. Energy97, 400-410.
  14. Shi, Z., Wang, X., & Guessous, L. (2010). Effect of compression on the water management of a proton exchange membrane fuel cell with different gas diffusion layers. Journal of fuel cell science and technology, 7(2), 021012.
  15. Tiss, F., Chouikh, R., & Guizani, A. (2013). A numerical investigation of the effects of membrane swelling in polymer electrolyte fuel cells. Energy conversion and management67, 318-324.
  16. Perng, S. W., Wu, H. W., & Wang, R. H. (2014). Effect of modified flow field on non-isothermal transport characteristics and cell performance of a PEMFC. Energy conversion and management80, 87-96.
  17. Abdollahzadeh, M., Pascoa, J. C., Ranjbar, A. A., & Esmaili, Q. (2014). Analysis of PEM (Polymer Electrolyte Membrane) fuel cell cathode two-dimensional modeling. Energy68, 478-494.
  18. Ruksawong, K., Songprakorp, R., Monyakul, V., David, N. A., Sui, P. C., & Djilali, N. (2017). Investigation of PEMFC under Static Magnetic Field: Temperature, Relative Humidity and Performance. Journal of The Electrochemical Society, 164(2), F1-F8.
  19. Gasbaoui, B., Nasri, A., Abdelkhalek, O., Ghouili, J., & Ghezouani, A. (2017). Behavior PEM fuel cell for 4WD electric vehicle under different scenario consideration. International Journal of Hydrogen Energy, 42(1), 535-543.
  20. Mao, L., Jackson, L., & Jackson, T. (2017). Investigation of polymer electrolyte membrane fuel cell internal behaviour during long term operation and its use in prognostics. Journal of Power Sources, 362, 39-49.
  21. Hong, P., Xu, L., Li, J., & Ouyang, M. (2017). Modeling and analysis of internal water transfer behavior of PEM fuel cell of large surface area. International Journal of Hydrogen Energy, 42(29), 18540-18550.
  22. Ahmed, D. H., & Sung, H. J. (2017). Water and thermal management in PEMFCs–influencing parameters and operational conditions: A Review. Journal of Alternative and Renewable Energy Sources, 3(1), 1-43.
  23. Jeon, D. H., Greenway, S., Shimpalee, S., & Van Zee, J. W. (2008). The effect of serpentine flow-field designs on PEM fuel cell performance. International journal of hydrogen energy, 33(3), 1052-1066.
  24. Jithesh, P. K., Bansode, A. S., Sundararajan, T., & Das, S. K. (2012). The effect of flow distributors on the liquid water distribution and performance of a PEM fuel cell. International journal of hydrogen energy, 37(22), 17158-17171.
  25. Khazaee, I. (2015). Experimental investigation and numerical comparison of the performance of a proton exchange membrane fuel cell at different channel geometry. Heat and mass transfer, 51(8), 1177-1187.
  26. Zhang, J., Tang, Y., Song, C., Xia, Z., Li, H., Wang, H., & Zhang, J. (2008). PEM fuel cell relative humidity (RH) and its effect on performance at high temperatures. Electrochimica Acta, 53(16), 5315-5321.
Volume 1, Issue 1
Winter 2025
Pages 25-35

  • Receive Date 16 September 2024
  • Revise Date 27 November 2024
  • Accept Date 24 December 2024
  • First Publish Date 25 December 2024